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Showing posts with label primary heat. Show all posts
Showing posts with label primary heat. Show all posts

Saturday, April 21, 2018

Global Heat Budget #2: Oceans


The world’s oceans are warming.  Ocean warming is the strongest confirmation that greenhouse gases are warming the planet. 

The heat capacity of water is among the highest of common substances.  That means that water can absorb a large amount of heat while its temperature changes only slightly.  The measurable warming of the world’s oceans indicates that a very large amount of heat has come from somewhere.  The only credible source for so much heat is the retention of heat by atmospheric greenhouse gases.  Let’s look at the source of the data, and the numbers.

ARGO Oceanographic Program
Rising ocean temperatures have been measured by oceanographic surveys since the 1970s.  However, these ocean surveys were limited in geographic coverage and continuity of data acquisition.  A more comprehensive system, ARGO, was put in place beginning in the early 2000s, with improvements and new deployments continuing today.  Today, ARGO consists of nearly 4000 floats which continuously measure ocean temperature, salinity, density and currents from the surface to 2000 meters. 
ARGO floats measure temperature to an accuracy of two-thousands (0.002) of a degree Celsius.  The floats are “parked” at 1000 meters, and every ten days submerge to 2000 meters and return to the surface, where data is broadcast to satellite receivers.  The system provides comprehensive coverage worldwide except for polar latitudes, and continuous measurements.

Ocean *Weather*
Like the atmosphere, ocean temperatures are seasonal, cyclic, variable, and turbulent.  The large number of ARGO floats was designed to adequately measure and characterize the variable temperatures of the ocean.  The volume of data acquired allow scientists to make maps of the changing water temperature and calculate the total heat content in the ocean.
Observations
Surface temperatures are warming the fastest.  NOAA presents charts of average ocean temperature and ocean heat content according to water depth, based on ARGO observations and earlier oceanographic studies.

Surface waters (0 – 100 m) have warmed by about 0.6 degrees C on average since the late 1960s. 
Intermediate waters (0 – 700 m) have warmed by a little over 0.2 degrees C on average since the late 1960s. 
Relatively deep waters (0 – 2000 m) have warmed by about 0.1 degree C on average, since the late 1960s.
Over all depth increments observed, the rate of warming seems to be slightly increasing.

Heat Content
The changing heat content of the ocean is a simple function of the change in temperature.  The heat capacity (or specific heat) of water represents the amount of heat required to change the temperature of a given volume of water.  From an observed change in temperature, we can back-calculate the amount of heat that has entered the ocean.  The density and heat capacity of water change slightly with pressure (and water depth).  NOAA has calculated the heat content of the ocean over various depth intervals from the temperature data and heat capacity.  

The heat content of the ocean at intermediate depths (0 – 700 m) has increased by about 2 x 1023 joules since the late 1960s. 
The heat content from the surface to 2000 meters (0 – 2000 m) has increased by about 3 x 1023 joules since the late 1960s.  This means that the heat content over the interval from 700 m to 2000 m has increased by about 1 x 1023 joules, about half of the increase in heat content at intermediate water depths.
Source of Increasing Heat
NOAA unfortunately did not report temperature change or heat content in separate depth intervals, but only in overlapping intervals of 0 – 100 , 0 – 700, and 0 – 2000 meters.  Starting from the average change of temperature for each interval, I calculated the heat content for 0 – 100 m, 100 – 700 m, and 700 – 2000 m.  My figure for total heat content calculated from temperature change exceeds the heat content reported by NOAA by 14%, probably due to errors in my single-point values for temperature or heat capacity over these depth intervals.
Temp Rise (C)
Volume (km3)
Density (g/cc)
Mass (kg)


Heat Capacity (J/kg-C)
Change in Heat Content (J)
0 - 100 m
0.6
5.23E+07
1.025
5.10E+19


3928.00
1.20E+23
0 - 700 m
0.2
3.69E+08
1.034
3.57E+20


3421.50
2.44E+23
0 - 2000 m
0.1
1.36E+09
1.329
1.02E+21


3339.04
3.41E+23
Intervals
Change in Heat Content
Percent of Heat Change
Change in Heat Content per 100 m
0 - 100 m
1.2E+23
35%
1.2E+23
100 m - 700 m
1.2E+23
36%
2.1E+22
700 m - 2000 m
9.6E+22
28%
7.4E+21

There is a large difference between the heat gained in the upper 100 meters of the ocean and the heat gained at deeper levels by equivalent volume.  The ocean is clearly heating from the surface downward.  About 35% of the total heat increase has occurred in the upper 100 meters of the ocean, about 36% in the next 600 meters, and about 28% in the next 1300 meters.  Research on deep ocean currents shows that heat is also being introduced into the deep ocean by currents, rather than by conduction. 

The geographic distribution of ocean heating also shows atmospheric influence.  The ARGO ocean data shows distinct heating anomalies between 30 and 40 degrees of latitude, north and south.  These are the down-welling points of large atmospheric convection cells termed Hadley cells.  You can see atmospheric circulation in observations of ocean warming.


Conclusion
The first post in this series quantified anthropogenic heating and cooling, primarily from greenhouse gases, particularly CO2.  This post looked at the largest heat sink on earth – the oceans.  

Net Anthropogenic heat absorbed by the planet from 1970 to 2016 was about 3.4 x 1023 joules.  Over the same period, the heat content of the oceans has increased by about 3.0 x 1023 joules.  Anthropogenic heat is the only credible source for the heat appearing in the ocean, and the warming oceans confirm that greenhouse gases are, in fact, warming the planet.  
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References
Global Heat Budget #1: Anthropogenic Heat



Ocean heat content figures.

Ocean temperature figures.

Gridded temperature data in map view.

The Oceans Their Physics, Chemistry, and General Biology, UC Press E-Books Collection, 1982-2004, University of California Press 
Physical properties of sea water.

Wednesday, April 11, 2018

Global Heat Budget #1: Anthropogenic Heat

I have been away from my blogs for far too long.  I will try to post a series on the global heat budget.

Previously, I posted a lot of work on atmospheric CO2, considering the geographic distribution, isotope data, rates of change, comparison to man-made emissions from various sources, and interaction of the atmosphere with global carbon reservoirs.  The latest summary post is here:
I deliberately avoided the question of climate change to focus on the science of atmospheric CO2.

For the past year, I’ve been studying on the problem of global warming (the first-order consequence of greenhouse gases) and climate change (the higher-order consequences of greenhouse gases).  And I’ve been posting less while I worked to understand the data.

I’m going to present what I’ve learned as a series of short posts, rather than writing a book.
The very short version is this:

The Global Heat Budget; The Very Short Version
People have raised the concentration of atmospheric CO2 by burning fossil fuels.  The volume of CO2 released by fossil fuels has increased sharply since about 1950, and continues to increase today.

CO2 and other greenhouse gases retain heat in the atmosphere.  The quantity of heat is easily calculated as a function of the concentration of CO2 in the air.  We can calculate the amount of heat that has been trapped to date, and we can forecast the heat that will be trapped in the future.

Heat is increasing in heat sinks on earth.  Observations show that the amount of heat appearing in earth’s heat sinks is approximately equal to the heat retained by greenhouse gases.  The heat is showing up as rising ocean temperatures, melting ice, and a warmer atmosphere.  The quantity of heat appearing in these systems has been measured by high-accuracy monitoring programs since about 2003.  The warming ocean accounts for about 95 percent of our estimates of anthropogenic heat.  Retained heat due to greenhouse gases is the only credible source for the heat appearing in heat sinks.

Sea-level is rising.  Sea level rise has been documented by tidal gauges for 130 years, and by high-accuracy satellite measurements since 1992.  The amount of sea level rise matches the observed volumes of melted ice, thermal expansion of the ocean, and ground-water extraction.  The fact of rising sea level confirms observations of melting ice and warming oceans.

Higher atmospheric CO2 concentrations are inevitable for the foreseeable future.  Quantitative forecasts of future heating indicate serious and expensive problems will develop for the nation & the world.
Atmospheric CO2 has risen as a consequence of fossil fuel emissions.  The following chart is my version of the Keeling Curve (http://dougrobbins.blogspot.com/2016/08/the-keeling-curve-and-global-co2.html) showing global CO2 concentration, including high-amplitude seasonal cycles in the Northern Hemisphere, and low-amplitude seasonal cycles in the Southern Hemisphere.
History of Study of CO2 as a Greenhouse Gas
The physics of CO2 as a greenhouse gas is settled science, based on published studies dating back over 150 years.  High accuracy programs to measure melting ice, ocean temperatures, and rising sea level have been in place in recent decades, long enough to yield conclusive results.

Carbon dioxide was first proved to be a greenhouse gas by John Tyndall in 1859, proving speculation that began in 1820.  The planet-wide effect of changing CO2 concentrations was calculated by the Swedish chemist Arrhenius and published in 1896.  Arrhenius was originally attempting to find the cause of the ice ages, but later recognized the possibility that fossil fuel emissions could change the climate, and published that result in 1906.  Quantitative measurements of CO2 and rising temperatures were published in 1938 by Guy Callendar.  Systematic global measurements of CO2 concentrations began in 1955 by Charles Keeling.  Satellite measurements of sea level rise began in 1992.  Satellite measurements of Antarctic and Greenland ice mass began in 2003.  Detailed, comprehensive and continuous measurements of ocean temperatures began in 2004.

Calculation of Heat Retained by Greenhouse Gases
Greenhouse gases are mostly transparent to wavelengths of visible light, which carry most of the energy from our sun.  Visible light strikes the earth and is converted to heat.  Normally, some portion of that energy is re-radiated into space as thermal infrared radiation.  But greenhouse gases are opaque to infrared wavelengths, and trap heat in the atmosphere as a function of the concentration of those gases.  As greenhouse gases have accumulated in the atmosphere, lower levels of the atmosphere have warmed.  Higher levels of the atmosphere have cooled, as more heat has been trapped near the surface.

NOAA publishes historical tables of the atmospheric heating coefficients (known by the awkward and uninformative phrase *radiative forcing*) for anthropogenic greenhouse gases, dating back to 1979.  The coefficients are prepared according to international standards, taking into account cloudiness and angle of solar incidence to yield a global average.  You can do the math yourself to calculate annual heat retained by each greenhouse gas, which I have done.  Carbon dioxide represents about two-thirds of the heat retained in the atmosphere by greenhouse gases.  Methane, nitrogen oxide, chlorofluorocarbons (CFCs) and minor greenhouse gases account for the rest of the heat retained by greenhouse gases. 
In 1979, greenhouse gases retained about 7 x 1021 joules.  By 2016, greenhouse gases retained about 1.2 x 1022 joules, an increase of 78% in annual heating.  It’s difficult to conceptualize how much heat is represented by 1022 joules.  A joule is about ¼ of a standard calorie – the heat required to raise a gram of water by one degree C.  It’s a small amount of heat.  But 12,000,000,000,000,000,000,000 joules is a lot of heat.  Later in this series, we’ll consider how the earth can absorb that quantity of heat, and where the heat is going.
Aerosols and Anthropogenic Cooling
Aerosols are the least-well quantified anthropogenic influence on earth’s climate.  Sulfate aerosols cool the atmosphere by making clouds more abundant and reflective.  Sulfates can originate from volcanic eruptions, but are also a common industrial pollutant.  Carbon black aerosols warm the atmosphere by absorbing sunlight. 

Sulfate emissions have dropped dramatically in the United States and Europe over the past 25 years, thanks to regulations intended to limit acid rain, but world-wide sulfate emissions have continued to grow.  The average global impact of sulfates and black carbon aerosols is shown in the following graphs, but the more significant impacts are regional.  South Asia suffers from the greatest carbon black emissions and impact, while China is now the source of most sulfate emissions.

IPCC Net Anthropogenic Heating and Cooling
The IPCC (International Panel on Climate Change) 5th Climate Assessment contains a table of anthropogenic heating and cooling coefficients.  The IPCC numbers for conventional greenhouse gases are identical to NOAA, but IPCC also recognizes other anthropogenic factors, which can both heat and cool the atmosphere.  These factors act by direct absorption of sunlight, or by a greenhouse effect that is restricted to certain levels in the atmosphere.  The IPCC recognizes the warming factors of tropospheric ozone (O3), stratospheric water vapor (H2O), black carbon on snow, and contrails.   IPCC recognizes cooling factors, including land-use changes (which affect the reflectivity of the earth), stratospheric ozone, and aerosols. 

Here is a chart based on IPCC data, showing anthropogenic heating and cooling coefficients (*radiative forcing*).

Primary Anthropogenic and Other Heat
Strangely, to me, the IPCC report makes no mention of another source of anthropogenic heat – the primary heat resulting from burning fossil fuels and nuclear plants, and secondarily, the primary heat resulting from deforestation.  The global heat from non-renewable sources is reported in the BP Statistical Review of World Energy.  The energy released by deforestation can be easily calculated from the volumes of carbon dioxide released, which is estimated in several sources.  These sources of heat represent about 5% and 1%, respectively, of the net anthropogenic heat reported by IPCC, and exceed several other minor sources of heat in the report.

Here is a chart showing the calculated anthropogenic heating and cooling, based on IPCC estimates for radiative forcing, plus heat from primary energy.
I considered and calculated the incremental accumulation of geothermal heat, due to the retention of heat by greenhouse gases.  Geothermal heat is normally in a steady state, with heat flux from the planet balanced by thermal radiation into space.  The quantity of heat retained is quite small, however, and not worth adding to the heat budget. 

Agriculture has a significant influence on the planet’s seasonal CO2 cycles, due to the preponderance of agriculture in the temperate Northern Hemisphere.  Changes in atmospheric CO2 necessarily imply changes in heat, through the reduction and oxidation of carbon.  Agriculture appears to be a zero-sum influence on the long-term heat budget but may be significant in seasonal climate modeling. 

Net Anthropogenic Heat
The net heating coefficient (*radiative forcing*) for all anthropogenic heating and cooling was about 2.4 watts/min 2011.  The global average for solar insolation at the top of the atmosphere is 1361 watts/m2.  About 1000 watts/mof the sun's radiation reaches the earth's surface.  Anthropogenic heat represents a small but noticeable increment to the natural heating of the earth by the sun, about 0.24% above the natural, steady state of solar heating and radiative cooling.

Using the IPCC heating and cooling numbers, plus primary heat, we see that net global anthropogenic heating was 9.8 x 1021  joules in 2011. That’s enough heat to melt about 29,500 gigatonnes of ice, or to bring 14,000 gigatonnes of water from room temperature to boiling.  Of course, the icecaps are much larger than 29,500 gigatonnes of ice, and the ocean is much larger than 14,000 gigatonnes of water.  So the changes we see in a single year are subtle.
Net anthropogenic heat from 1970 to 2016 is about 3.4 x 1023 joules.  The effect of heat retained by greenhouse gases is cumulative. Over time, the consequences are not so subtle.  In the next few posts, we will look at how anthropogenic heat is being distributed in earth’s heat sinks.  
-------------------------------------------
References
NOAA Radiative Forcing Tables

IPCC climate change references
31 page Summary

VOX article on BECCS (Bio-energy and Carbon Capture and Sequestration) requirement to keep temperatures less than 2 degrees higher than pre-industrial levels.

2013 Full IPCC report, 1500+ pages

Fourth National Climate Assessment



BP Statistical Review of World Energy
Primary Heat from Fossil Fuels and Nuclear Energy

Primary Heat from Deforestation
Primary heat calculated from CO2 released.
Houghton, R.A. 2008. Carbon Flux to the Atmosphere from Land-Use Changes: 1850-2005. In TRENDS: A Compendium of Data on Global Change. Carbon Dioxide Information Analysis Center, Oak Ridge National Laboratory, U.S. Department of Energy, Oak Ridge, Tenn., U.S.A.


Aerosols
IPCC 5th Climate Assessment, pg. 1446.

Aerosols caused by human activity play a profound and complex role in the climate system through radiative effects in the atmosphere and on snow and ice surfaces and through effects on cloud formation and properties. The combined forcing of aerosol–radiation and aerosol–cloud interactions is negative (cooling) over the industrial era, offsetting a substantial part of greenhouse gas forcing, which is currently the predominant human contribution. The magnitude of this offset, globally averaged, has declined in recent decades, despite increasing trends in aerosol emissions or abundances in some regions. (emphasis mine).

By nucleating a larger number of smaller cloud drops, aerosols affect cloud radiative forcing in various ways. (A) Buffering in nonprecipitating clouds. The smaller drops evaporate faster and cause more mixing of ambient air into the cloud top, which further enhances evaporation. (B) Strong cooling. Pristine cloud cover breaks up by losing water to rain that further cleanses the air in a positive feedback loop. Aerosols suppressing precipitation prevent the breakup. (C) Larger and longer-lasting cirrus clouds. By delaying precipitation, aerosols can invigorate deep convective clouds and cause colder cloud tops that emit less thermal radiation. The smaller ice particles induced by the pollution aerosols precipitate more slowly from the anvils. This can cause larger and longer-lasting cirrus clouds, with opposite effects in the thermal and solar radiation. The net effect depends on the relative magnitudes.





Tuesday, July 4, 2017

The Global Heat Budget

Something odd is going on in the oceans. 

The oceans are apparently becoming more efficient at absorbing greenhouse gas heat from the atmosphere. Or, we are becoming better at quantifying the amount of man-made heat entering into earth systems.

According to published figures, the percentage of greenhouse gas heat entering the ocean has risen from less than 50% in the 1970s to over 92% today.  While the data from earlier years might be suspect, recent, high-quality data confirms the earlier pattern. The apparent change suggests we need to understand the cause of the higher rate of heat transfer to the oceans.  It may be that the rising rate of heat transfer is due to higher air temperatures, or there may be another explanation for the change.  If the rising rate of heat transfer is real, it begs the question of what was happening to the excess heat in earlier years.

In this post, I include other sources of man-made heat to calculate a world heat budget, comparing the quantity of man-made heat with the quantity of heat observed entering the oceans, atmosphere and melting ice.

Part I.  Anthropogenic Heat
Greenhouse Gases
In this post, we’ll look at the earth’s heat budget relating to greenhouse gases and other man-made sources of heat.   Greenhouse gases retain heat in the atmosphere, because they are transparent to much of the sun’s radiation spectrum, but opaque to most of the infrared thermal radiation.  Visible radiation from the sun penetrates the atmosphere and strikes the earth, but is trapped after being converted to infrared thermal radiation, instead of radiating back into space.  Increasing concentrations of greenhouse gases trap increasing amounts of the sun’s heat. 

We can calculate how much heat is retained, depending on the concentration of the gas.  We can look at the history of how greenhouse gas concentrations have changed, and calculate how much heat was retained a few years ago as compared to today.  And we can forecast how much heat will be retained in the future, and estimate what will happen because of the extra heat.

The amount of heat trapped by greenhouse gases was measured in laboratory measurements beginning in the late 1800s.  The Swedish chemist Arrhenius calculated the planetary warming that would result from doubling the amount of CO2 in the air, and published his results in 1896.   The high-altitude chemistry of the atmosphere was measured in high-altitude flights around the globe, improving the estimates of how much heat was trapped at varying concentrations of greenhouse gases.  Upcoming satellite missions will define the incoming and outgoing heat budget with even greater detail, unless cancelled by the current administration. 

The National Oceanic and Atmospheric Administration publishes a measure of the heat retained due to greenhouse gases, termed radiative forcing, reported in units of watts per meter squared (W/m2), equivalent to joules per second per meter squared (J/sm2).  NOAA's figures are global averages, with corrections for angle of incidence and cloudiness included.  From radiative forcing, we can calculate the global heat retained by each gas by multiplying by the cross-sectional area of the earth, and the time interval of interest.  Here is the annual global heat retained by various greenhouse gases, as reported by NOAA.  The heat retained by non-CO2 greenhouse gases was extrapolated for years that no data was available (1955 – 1978), assuming a constant ratio to CO2 for the earliest data available. 
Figure 1.  Annual Heat from Greenhouse Gases
The annual heat retained by greenhouse gases has increased by 75% since 1979, driven primarily by increases in atmospheric CO2 concentrations. 

The amount of heat retained by greenhouse gases is huge.  The annual heat retained by greenhouse gases in 2016 is 1.23 x 1022 joules, which is equivalent to about 533,000 Hiroshima-sized atomic bombs, every day, or one bomb a day on a grid of about 20 miles spacing, all over the world.  Fortunately, only a small fraction of that heat remains in the atmosphere, as we will see when we discuss heat sinks.

Primary Heat from Fossil Fuels, Nuclear Energy and Deforestation
For completeness and to give a sense of scale to the greenhouse effect, we can add other man-made additions to the earth’s heat budget.  Primary heat from fossil fuels and nuclear energy is published by the Energy Information Administration.  The volumes of biomass consumed by deforestation are uncertain, but I used published figures to estimate the primary heat derived from deforestation, through combustion or decay, using thermal values for combustion of wood, after corrections for moisture.

                Heat from Agriculture
Heat from agriculture is another source of anthropogenic heat, through the decay, combustion or consumption of agricultural biomass.  For the volume of agricultural biomass, I used data from the United Nations Environment Programme for the year 2009, and scaled that number in other years in proportion to world population.  Agricultural biomass displaces natural biomass, so I assumed an arbitrary 50% gain in productivity in agricultural biomass, as a result of irrigation and fertilizer.  I again used the thermal values for the combustion of wood, after corrections for moisture.

The sum of these inputs provides the history of human-caused heat to the earth’s heat budget, from 1955 – 2016.
Figure 2. Man-made Heat from All Sources, 1955 - 2015.

Part II.  Heat Sinks
To understand climate change, it is necessary to understand what happens to the heat retained by greenhouse gases.  Where is the heat going, and what is it doing to the planet?   The goal is to quantify the heat budget for the earth, and look at how it has changed over the past several decades. 

There are three main heat sinks we can measure: the ocean, the atmosphere, and volumes of melted ice.  I have used different methods to estimate the heat consumed by these processes, depending upon the data available.  It is quickly apparent that the ocean is the most significant heat sink.

Ocean Temperature
The temperature distribution of the ocean is seasonal, heterogeneous, and changing.  Maps of ocean temperatures at various depths can be seen on NOAA’s website.  Temperature data prior to 2000 was dependent on ship tracks, and variable methods of data collection.  These datasets had clusters of dense measurements in shipping lanes, and large gaps with no data.  The calculation of heat content is somewhat uncertain.  Beginning in 2000, NOAA launched ARGO, a system of free-floating buoys measuring ocean temperatures.  Today there are 3849 active buoys, which periodically dive to depths of 2000 meters, measuring temperatures within one-thousandth of a degree C, and returning to the surface every ten days to broadcast measurements to satellite receivers.  Here is a map of the current buoy locations. 

Figure 3.  Map of Current Location of ARGO Temperature Buoys, June 27, 2017.

The temperature rise noted over the past 50 years is relatively small, at 0.1 degrees C, but is two orders of magnitude more than the sensitivity of the ARGO instruments.  This temperature change represents an enormous amount of heat because of the huge volume of water and large heat capacity of the ocean.  As we might expect, the temperature of the shallow ocean is rising much faster than the temperature of the deep ocean.
Figure 4.  Ocean Temperature 0 -- 100 meters, NOAA
Figure 5.  Ocean Temperature 0 – 700 meters, NOAA
Figure 6.  Ocean Temperature 0 – 2000 meters, NOAA
The National Oceanographic and Atmospheric Administration (NOAA) published a chart of ocean heat content from 1957 through 2016.   NOAA did not publish the specific data used to generate the plot, so I have made an eye-ball fit to the data using a smooth function in Excel.   The NOAA chart, and my overlay of a smoothed function, is shown below.  The smoothed function allows me to calculate the annual change in ocean heat content.  As we will see when we compare heat sources to heat sinks, the heat absorbed by the ocean is very close to the amount of heat retained in the atmosphere by greenhouse gases.

Figure 7.  Cumulative Ocean Heat Content, NOAA, 1956 - 2016.
Figure 8.  Annual Change in Ocean Heat Content.
Figure 8 shows the annualized change in ocean heat content from my smoothed version of NOAA’s heat content chart, 0 – 2000 meters.  The change in heat content is constantly positive, but the rate of change dipped in the 1960s, before a continuous acceleration in heat content from the 1970s to the present.

Atmosphere
Similarly, the National Aeronautics and Space Administration (NASA) published a table of average global surface air temperatures. 
Figure 9.  Surface air temperature, 1880 – 2016, NOAA.

Figure 10.  Surface air temperature, 1955 – 2016, with polynomial regression to the data, NASA.
Assuming that the surface temperature change is representative of the atmosphere as a whole (or at least, the majority of the heat content), I calculated the annual change in atmospheric heat content.  The heat content of the atmosphere is significantly smaller than the heat content of the oceans despite a larger change in temperature, due to the very high heat capacity of water compared to air. 

Figure 11.  Annual change in Atmospheric Heat Content.
Melting Ice
NASA has used satellites and overflights to measure the changing volumes of ice on the Antarctic and Greenland ice sheets.  The determinations have been based on a combination of satellite gravity measurements, surface elevation measurements, and ice-penetrating radar measurements (from overflights).   Most of the high-quality surveys have occurred since the early 2000s, in particular NASA’s GRACE  (Gravity Recovery and Climate Experiment) gravity-measurement satellite, which was launched in 2002.
Figure 12.  Mass loss in Antarctica measured by NASA's GRACE satellite.

Figure 13.  Mass loss in Greenland measured by NASA's GRACE satellite.
Separately, the volumes of continental glaciers and ice sheets (other than Greenland and Antarctica) have been separately studied through an inventory of photos and elevation maps, and published as a time-series of melted ice volumes.  Volumes of melted ice from all three sources were reported in a single chart by Shuang Yi, et al, 2015.  As I did with NOAA data for oceans and temperatures, I fitted a smooth polynomial function to the published charts, and then extracted the annual change in melted ice for all three sources.  I should note that mass-loss data from NASA’s GRACE satellite shows about 10% smaller volume of ice loss than Shuang et al.  Shuang et al presumably incorporated other sources of information, including ice-penetrating radar, altimetry and flow measurements from other studies.

Figure 14.  Ice Loss from Antarctica, Greenland, and other Glaciers, Shuang Yi et al, 2015, with overlay of smoothed polynomial functions.
Image Credit:  Shuang Yi et al, 2015.

Finally, I calculated a volume of ice melted in the Arctic sea-ice, based on simple assumptions of new ice thickness (1 m) and multi-year ice (2 m), and the changing areas reported for new and multi-year ice.   The volume of melting Arctic sea-ice is relatively trivial compared to the volumes melting from glaciers and ice-sheets, but is still indicative of the overall melting trend in the Arctic.
Figure 15.  Diminishing Arctic Sea Ice, 1953 - 2010, image credit, National Snow and Ice Center.
I assumed that the volume of ice would need to be heated by 10 degrees Celsius before melting, based on temperature profiles from drilling on the Greenland and Antarctic ice sheets.  I then applied the heat of crystallization to the volumes of ice melted to obtain the total heat absorbed by melting ice. 
Figure 16.  Heat consumed by Global Melting Ice, 2004 – 2015.
The sum of oceanic, atmospheric, and melting ice heat sinks is shown below.  The ocean is by far the dominant heat sink. 
Figure 17.  Global Heat Absorbed by Heat Sinks.
Despite all of the news about rising atmospheric temperatures and volumes of melted ice, the ocean is absorbing the lion’s share of heat around the earth.  By comparison to the oceans, heat consumed by atmospheric heating and melting ice is negligible.  In 2016, the ocean absorbed about 96% of rising heat, compared to a little over 1% for the atmosphere, and 3% for melting ice. 

Part III.  The Heat Budget:  Retained Heat and Heat Consumed
Greenhouse Gas Heat and Ocean Heat Content
The simplest (but incomplete) expression of the planetary heat budget is the comparison between annual heat retained by greenhouse gases and the rising heat content of the oceans. 
Figure 18.  Annual Greenhouse Gas Heat and Annual Change in Ocean Heat Content
The first observation to make from this chart is that heat retained in the atmosphere by greenhouse gases and heat warming the oceans are very close to the same quantities. Greenhouse gases are retaining about 1,000,000,000,000,000,000,000 joules of excess heat in the atmosphere annually, and about 1,000,000,000,000,000,000,000 joules of unexplained heat is showing up annually in the oceans.  There is no known natural source of new heat warming the oceans.  It cannot be a coincidence.

The second, startling observation from this chart is that the rate of heat transfer from the atmosphere to the oceans is changing.  The amount of heat annually absorbed by the oceans apparently fell in the 1960s, although the data supporting this observation is weak.  However, continuing forward into the era of good data, the volume of heat absorbed by the oceans since 2000 has rapidly increased, and the fraction of  man-made heat absorbed by the oceans has also rapidly increased.  As temperatures rise, the oceans appear to be becoming more efficient at absorbing heat from the atmosphere.  

This raises a number of questions.  First, is the measurement of ocean heat content correct?  The quality and sensitivity of the ARGO system would suggest that the numbers are good since 2004. Second, are the calculations for man-made heat correct?  These numbers contain many assumptions, and are more likely to be uncertain than the ocean heat content.  Or third, was there another heat sink functioning in prior years, which is no longer working?  This seems unlikely.  Rather, the effort to align the sources and sinks in the earth's heat budget should focus on better quantifying of the sources of man-made heat.  

Full Heat Budget: Anthropogenic Heat and Heat Consumed in Heat Sinks
We can compare all sources of man-made heat from Part I to all heat sinks identified in Part II, to construct a heat budget for human-induced climate change.   Let’s look again at all sources of man-made heat, 1955 – 2015.
Figure 19.  Anthropogenic Heat, 1955 – 2015.
The red line indicates the sum of all man-made heat added to the earth’s atmosphere.

And let’s look again at the heat taken up by the oceans, atmosphere and ice.  As we noted before, the amount of heat entering the ocean overwhelmingly dominates heat entering the atmosphere or melting ice.
Figure 20.  Heat sinks, 1955 – 2015.
Let’s combine the two charts to see the full heat budget. 
Figure 21.  Man-made Heat and Heat Sinks, 1955 - 2016.
As we see, the gap between known sources of man-made heat and the observed amount of heat entering earth systems has narrowed, primarily due to an increasing amount of heat observed entering the oceans.  The amount of man-made heat that we can observe entering the oceans has risen from about 40% in the 1970s to nearly 90% today.  Much of that difference is probably due to the inadequacy of data prior to the deployment of the ARGO system of ocean buoys in the early 2000s.  However, there is a very real possibility that it also reflects a physical change in the process of transferring heat from the atmosphere to the ocean.

Let’s exclude questionable data, and only look at data from 2004.  First, man-made heat:  
Figure 22.  Anthropogenic Heat, 2004 – 2016.
And second, the heat budget including heat sinks in the oceans, atmosphere, and melting ice.
Figure 23.  Global Heat Budget, 2004 - 2016.
We are still left with the striking observation that between 2004 and 2016 the fraction of man-made heat absorbed by the ocean changed from 67 percent to 87 percent.  Given the high quality of recent observations, it seems that this is a real change in the rate of heat absorption by the ocean. 

Conclusions
People are the cause of rising temperatures and melting ice on earth.  Rising temperatures are observed in the atmosphere and oceans, and accelerating melting of ice in glaciers, arctic sea ice, and the Greenland and Antarctic ice sheets.  The heat responsible for these changes can be quantified and compared to the heat known to be retained in the atmosphere by human activities: CO2 and other greenhouse gases, primary heat from energy production, primary heat from deforestation, and heat produced from agricultural biomass.  There is a close correspondence between the quantity of man-made heat and observed heat appearing in natural systems; 89% of the heat generated by humans can be accounted for in known heat sinks.  Further, there is no known natural process which can be observed and measured presently warming the earth.

In more striking terms, people added 13,800,000,000,000,000,000,000 joules of heat to the atmosphere in 2016.   We observed 12,500,000,000,000,000,000,000 joules appearing in oceans, atmosphere, and melting ice with no known alternative cause.  This is not a coincidence.

The largest source of man-made heat is carbon dioxide from fossil fuels, which accounts for 57% of heat input into the Earth’s heat budget.  Greenhouse gases other than CO2 account for an additional 32%, bringing the total fraction due to greenhouse gases to 89% of man-made heat.  When I began this project, I focused on only greenhouse gases, but I found that heat appearing in heat sinks exceeded 100% of the heat retained by greenhouse gases.  I then added other sources of man-made heat that occurred to me: primary heat from fossil fuels and nuclear energy, primary heat from deforestation, and primary heat from the decay of agricultural biomass.  These other sources account for a smaller, but significant 11% fraction of man-made heat.

Large quantities of heat are retained in the atmosphere prior to absorption by other heat sinks.  Heat from human sources is put into the atmosphere before being transferred other to heat sinks.  Total man-made heat delivered to the atmosphere is equivalent to about 585,000 Hiroshima-sized bombs (533,000 from greenhouse gases alone) exploding in the atmosphere daily, or on a world-wide grid with a spacing of about 17 miles.  It seems likely that there will be increasingly severe consequences to weather systems, as such quantities of heat are moved from the atmosphere to their ultimate repository in heat sinks. 

Oceans are absorbing the bulk of heat produced by humans.  Oceans are absorbing 96% of the heat that can be observed going into heat sinks on earth; with atmospheric warming and melting ice accounting for only about 1% and 3% of the heat we can observe going into heat sinks.  If the oceans were not absorbing heat from the atmosphere, average temperatures would increase by 5 degrees C in about two years, equivalent to the temperature change between the current climate and the ice ages.   Without oceans on earth to absorb heat, man-made heat would quickly destroy civilization.  As climate scientist John Abraham said, “Global warming is really ocean warming.”

The fraction of man-made heat absorbed by the oceans is increasing rapidly, according to recent, high quality data.  The fraction of man-made heat absorbed by the ocean rose from 67% to 87% between 2004 and 2016.  The cause of the changing rate of heat absorption is not known.  Some likely possibilities include higher air temperatures and increased wave and wind activity at the ocean’s surface.

Explanations matter.  As I wrote in an earlier post, science is about delivering explanations in terms of physical processes.  Unfortunately, I could not find any physics describing the rate of heat transfer between the atmosphere and the ocean.  It is certain that higher surface air temperatures will mean a higher rate of heat transfer to the ocean, but it would be good to quantify that effect.  Other aspects of climate change, such has higher wind speeds and larger waves, may also play an important role.  Identifying the processes involved and quantifying the rate of heat transfer is unfinished work.

Future predictions of the consequences of anthropogenic heat depend on understanding the changing rate at which the ocean is absorbing heat from the atmosphere. 

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Appendix I.
Other Potential Sources of Heat
When I began this study, the only source of anthropogenic heat I considered was from greenhouse gases.  I calculated the heat retained by greenhouse gases based on NOAA’s on-line publication of annual radiative forcing figures for each kind of greenhouse gas.  When I calculated the heat absorbed by heat sinks for 2015, I found that new heat showing up in earth systems exceeded the heat from greenhouse gases by a little bit.  So I went looking for other sources of man-made heat, and added primary heat from energy production, primary heat from deforestation, and net heat resulting from agriculture.  This brought the heat observed in earth systems to less than the sources of anthropogenic heat.

But the rapidly changing heat content of the ocean concerns me, and makes me think that I have not yet captured all of the sources of anthropogenic heat, or properly quantified heat from greenhouse gases.  In particular, it seems to me that published figures on radiative forcing are only considering the proportion of the sun’s radiant heat which is retained in the atmosphere due to the greenhouse effect.  However, greenhouse gases will affect all out-going thermal radiation from earth.  Thus, geothermal heat will also be retained in the earth’s atmosphere by greenhouse gases.  Geothermal heat is a steady-state process, adding about 1.4 x 10^21 joules to the earth’s heat budget (about 10% of total anthropogenic heat).  I ignored geothermal energy in this study because it is constant.  But if the amount of geothermal energy retained in the atmosphere is changing due to greenhouse gases, I may need to add additional heat to the analysis.  Similarly, natural biomass is a large part of the earth’s heat budget.  Like geothermal heat, I assumed that it is constant (except where displaced by agriculture).   Presumably, heat from all natural biomass is accounted for in the sun’s radiant heat, and therefore accounted for in the radiative forcing figures published by NOAA.  But it might be worth a question for clarification.  

Appendix II.

Assumptions for Global Heat Budget study: 
I made a number of simplifying assumptions in order to calculate the global heat budget.  Those assumptions are fairly sweeping in some cases, but all are based on reasoning, as explained below, and the results of the study are robust with respect to the simplifying assumptions made.

NOAA published data for radiative forcing for fifteen greenhouse gases other than CO2, for the years 1979 – 2016.   I extrapolated the radiative forcing for these gases for the years 1979 – 1974, scaling the radiative forcing for non-CO2 gases proportionally with CO2 for the years 1955 – 1978, for Figures 17, 18 and 20.

I assumed that volumes of deforestation biomass decayed or were burned, generating heat according to the heat content of wood fuel with an initial moisture content of 50%.  I used published figures for annual deforestation biomass through 2008, and assumed deforestation was constant at 2008 levels for all later years.

I assumed that net agricultural biomass was proportional to global population, and scaled reported biomass from 2009 for each year accordingly.  I also arbitrarily assumed that agricultural biomass productivity was 50% greater than the natural productivity it displaced, allowing me to calculate the net heat attributable to agricultural production, in excess of natural biomass production.   I assumed that the heat produced during decay is equal to the heat of combustion for wood, after corrections for moisture content.  Moisture was assumed to be 50%.  The heat of combustion for dry wood was used to calculate heat produced from dry agricultural biomass during decay.

I used a smooth 2nd order polynomial function for global ocean heat content (0 – 2000m).  I created the function as a visual overlay on NOAA’s plot of heat content, as I was unable to obtain digital data from NOAA for this parameter.

I used smooth 2nd order polynomial functions for ice melt from Greenland, Antarctica and other Glaciers and Ice Sheets, created by visual overlays on a figure from Shuang, 2015.  The functions for Antarctica and Greenland compare very well (about 10% higher) to digits available from NASA for the gravity-indicated mass losses from Greenland and Antarctica.  Numerous papers document ice loss from other glaciers and ice sheets, but without documented volumetric data.

I estimated the thickness of “multi-year [‘old’] ice” as 2 meters, and “new ice” as 1 meter, in calculating loss of Arctic sea ice.   Old ice diminished from 1,860,000 km2 in 1984 to only 110,00 km2 in 2016, a decline of 96%.   (Imster, E., in EarthSky, Nov. 8, 2016). Declining areas of multi-year ice and new ice were calculated separately, and attributed as a constant annual average, resulting in an estimate of 145 gigatonnes of Arctic sea ice melted annually. 

I assumed that all ice needed to be warmed 10 degrees C before melting.  This figure was an eyeball estimate based on temperature profiles of ice cores in Antarctica and Greenland.

I used a figure for the heat capacity for the atmosphere from college physics lecture notes available on-line.  I assumed that the temperature of the atmosphere changed proportionately with surface temperature when calculating atmospheric heat content.  I would note that recent satellite studies have shown that the troposphere is cooling, perhaps as the result of greater water content.  In any event, the bulk of the atmosphere’s mass, density and heat content are near the surface. 
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References:

Heat Sources
Greenhouse Gases
James.H.Butler and Stephen.A.Montzka, 2017,  THE NOAA ANNUAL GREENHOUSE GAS INDEX (AGGI),
NOAA Earth System Research Laboratory
Source for radiative forcing data used in greenhouse gas heat calculations.

Fossil Fuels
Conti, J., et al, 2013.  International Energy Outlook, U. S. Energy Information Administration, Office of Energy Analysis, U.S. Department of Energy, Washington, D.C.    DOE/EIA-0484(2013)
http://www.eia.gov/forecasts/ieo/

U.S. Energy Information Agency, Data Tables, U.S. Energy Information Agency, Office of Energy Analysis, U.S. Department of Energy, Washington D.C. data tables, 2014
Source for data on primary heat from fossil fuel and nuclear energy.

Deforestation
Houghton, R.A. 2008. Carbon Flux to the Atmosphere from Land-Use Changes: 1850-2005. In TRENDS: A Compendium of Data on Global Change. Carbon Dioxide Information Analysis Center, Oak Ridge National Laboratory, U.S. Department of Energy, Oak Ridge, Tenn., U.S.A.
Source for biomass used in calculation of primary heat generated by deforestation.  Volumes of deforestation were assumed constant after 2008.

Adam Martin, 2011, A Reassessment of Carbon Content of Tropical Trees.  Average carbon content of dry wood is 47.2%.  This analysis includes volatiles, determined by the process of freeze-drying, instead of heat-drying the wood.

Agriculture
UNEP, 2009, Converting Waste Biomass Into a Resource

Heat Sinks
Atmosphere
NASA, 2017, Global Annual Mean Surface Air Temperature Change
Tabular data and chart

Dennis Hartman, 2017, University of Washington, Heat capacity of ocean, atmosphere and land.
Heat capacity of atmosphere used to calculate changing heat content.

Oceans
NOAA, National Centers for Environmental Information
Source of charts used with overlays to generate smoothed functions for ocean heat content and temperature.  Note: the charts showing average ocean temperature changes for 0 – 700 meters and 0 – 2000 meters were accessed on this site in June, 2017, but are no longer available.

The ARGO system and the Jason altimeter system allow separation of sea level rise into steric (heat & salinity; i.e. density) and mass components.   The steric component is dominant over the mass component in regional sea level variability and on a global basis it accounts for about 1/3 of total sea level increase in the past half century (Domingues et al 2008).

specific heat of seawater = 3.9 joules/g

John Abraham, 2017, New study confirms the oceans are warming rapidly, The Guardian.
Dr. John Abraham is a professor of thermal sciences. He researches in climate monitoring and renewable energy generation for the developing world. His energy development work has extended to Africa, South America and Asia.  “Global warming is really ocean warming.”

Ice Melt
Greenland, Iceland, and Antarctica
Shuang Yi, Wenke Sun, Kosuke Heki, and An Qia, 2015, An increase in the rate of global mean sea level rise since 2010, Geophysical Research Letters

NASA Global Climate Change, Vital Signs of the Planet
Source of charts and data tables for ice mass loss from Greenland and Antarctica.

Contribution of ice sheet and mountain glacier melt to recent sea level rise
J. L. Chen, C. R. Wilson, & B. D. Tapley

Arctic Sea Ice
Imster, E., in EarthSky, Nov. 8, 2016, Decline of Arctic’s thickest sea ice.  Multi-year ice grows up to 4 meters thick, while single-year ice is 2 meters thick at most.  The area covered by Arctic sea ice at least four years old has decreased from 1,860,000 square kilometres in September 1984 to 110,000 square kilometres in September 2016.